The Chemistry of Krypton, Xenon and Radon

Diastereomeric selective formation of a linear diphosphazane: meso-iso-PrN[PhP(iso-PrNH)]2

“…C(25) -2421 ( 4) 2139 (3) -1348 ( 2) 81 ( 1) C( 26) -1536 ( 4) 2607 (2) -562 (2) 60( 1) 2) 1280 ( 2) 57 ( 1) C(28) -2315 ( 4) 6101 (3) 1782 ( 3) 85 ( 1) C(29) -4873 ( 3)…”

“…i v i d u a l n o t d i r e c t l y a s s o c i a t e d w i t h s c i t e i s p r o h i b i t e d . Mo(l)-C( l)-O(l) 179.0 (2) Mo(l)-C(4)-0(4) 179.7 (4)Mo(l)-C(3)-0(3) 179.7(2) …”

Radon hydrides: structure and bonding

“…After Bartlett's synthesis of the first noble gas complex Xe + [PtF 6 ] À in 1962, 1 a plethora of such molecules has been reported. [2][3][4][5][6][7][8][9] Radon, however, is an exception. Because of its price and radioactivity, experimental chemical research involving this element is rarely performed.…”

Tautomerism in Xenon Hexafluoride: An Investigation of Xenon Hexafluoride and its Complexes by Raman Spectroscopy

“…This is consistent with the representation of E-Fb as three-center-four-electron bonds, in consequence of as which the Fb ligands bear considerable negative charge. 40 The negatively as charged Fb will experience increased attraction to E as the nuclear as charge of that atom increases and F which is to be viewed as electroneq pair bonded to E, will be closer to charge neutrality than F and its bas attraction to E will in consequence be less dependent upon Z of E. RuF 6 ] is summarized in Table 3;…”