Activating Unreactive Substrates 2009
DOI: 10.1002/9783527625468.ch2
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The Chemistry of Superbasic Guanidines

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Cited by 5 publications
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“…Our own group has a long-standing interest in imidazolin-2-imine ligands, which can be regarded as particularly basic (superbasic) guanidine ligands. Thereby, bidentate ethylene-bridged and tridentate pyridine-bridged bis­(imidazolin-2-imine) ligands have found widespread use in organometallic and coordination chemistry. In view of the enormous interest in ferrocene-based ligands (vide supra), we set out to investigate ligands such as fc­(NIm) 2 ( 1 ) and their coordination chemistry. As indicated by the mesomeric forms 1 A and 1 B in Scheme , this ligand can be expected to act as a particularly strong N-donor toward transition metals because of the ability of the imidazole moiety to efficiently stabilize a positive charge .…”
Section: Introductionmentioning
confidence: 99%
“…Our own group has a long-standing interest in imidazolin-2-imine ligands, which can be regarded as particularly basic (superbasic) guanidine ligands. Thereby, bidentate ethylene-bridged and tridentate pyridine-bridged bis­(imidazolin-2-imine) ligands have found widespread use in organometallic and coordination chemistry. In view of the enormous interest in ferrocene-based ligands (vide supra), we set out to investigate ligands such as fc­(NIm) 2 ( 1 ) and their coordination chemistry. As indicated by the mesomeric forms 1 A and 1 B in Scheme , this ligand can be expected to act as a particularly strong N-donor toward transition metals because of the ability of the imidazole moiety to efficiently stabilize a positive charge .…”
Section: Introductionmentioning
confidence: 99%