The Choice of Substrate Material and Electrodeposition of High Purity Niobium Coatings

Abstract

The interaction of different materials with the niobium containing melt was investigated. As substrate materials the ceramics, beryllium and carbopyroceram were chosen. Several spherical ceramic and beryllium samples were coated with protective molybdenum film by magnetron sputtering. After the experiment (exposition time 10 min) the exfoliation of molybdenum film from ceramic samples was observed due to interaction of the substrate with the melt. The beryllium samples regardless of the shape and the presence of the protective films were dissolved in the niobium containing melt due to more negative electrode potential comparing with niobium one. The carbopyroceram samples were exposed in the melt during 3 and 12 hours. It was found that the carbopyroceram it not corrodes in the niobium containing melt. The optimal regimes for electrodeposition of smooth uniform niobium coatings with the thickness up to 50 µm on carbopyroceram spheres were found.

Electrolytic superconducting niobium coatings for a cryogyroscope rotor: creation and properties

“…A glassy carbon crucible SU-2000 brand was used as a container for the melt in the processes of elecrodeposition, a spherical sample of carbopyroceram was used as a cathode, and a crucible lining made of niobium was an anode [2]. The conditions and electrolytic method for obtaining a superconducting niobium coating on the cryogyroscope rotors require the creation of a high-purity atmosphere of an inert gas (argon).…”