Given a graph G of order n, the σ‐polynomial of G is the generating function σ(G,x)=∑aixi where ai is the number of partitions of the vertex set of G into i nonempty independent sets. Such polynomials arise in a natural way from chromatic polynomials. Brenti (Trans Am Math Soc 332 (1992), 729–756) proved that σ‐polynomials of graphs with chromatic number at least n−2 had all real roots, and conjectured the same held for chromatic number n−3. We affirm this conjecture.