Abstract. The purpose of this article is to describe connections between the loop space of the 2-sphere, Artin's braid groups, a choice of simplicial group whose homotopy groups are given by modules called Lie(n), as well as work of Milnor [25], and Habegger-Lin [17,22] on "homotopy string links". The current article exploits Lie algebras associated to Vassiliev invariants in work of T. Kohno [19,20], and provides connections between these various topics.Two consequences are as follows: (1) the homotopy groups of spheres are identified as "natural" sub-quotients of free products of pure braid groups, and (2) an axiomatization of certain simplicial groups arising from braid groups is shown to characterize the homotopy types of connected CW -complexes.