The configurations at C-9 of the cinchona alkaloids

Electron transfer in groups of iron, cobalt, and copper triazene 1-oxides: Hammett correlation, ligand redistribution, and crystal field effects

“…(8) Equation 6then becomes eq 9. Here£f°a nd H°are symbols FAE°= -A(AH[°) (9) for entropy and enthalpy, respectively. In eq 9 the variation in each quantity is measured in the sense (X = X) -(X = H).…”

“…Hence the recent interest in this area. [9][10][11][12][13][14][15][16][17][18] In this context the transition-metal complexes19-24 of triazene 1-oxides, RN(0)= (1) George, P.; McClure, D. S. Prog. Inorg.…”

NMR Spectroscopic Determination of Preferred Conformations of Quinidine and Hydroquinidine

“…The mass spectra of both 1 COOCH,, 111 compounds showed molecular ion peaks at mle 518 and typical peaks for ihoga alkaloids at m/e 136 and 124 (4). Assignment of Structures I1 and I11 to the two major substitution products was done primarily on the basis of PMR and mass spectra.…”

N-[(2-Chloro-8-methylquinolin-3-yl)methyl]-4-methoxyaniline

“…For background to quinoline compounds, see: Elderfield (1960); Wright et al (2001); Sahu et al (2002); Bringmann et al (2004); Kournetsov et al (2005). For the biological and pharmaceutical applications of quinolines, see: Albert & Ritchie (1955); Mouzine et al (1980); Lyle & Keefer (1967). For the general synthesis of quinolines, see: Cope & Ciganek (1963); Ohta et al (1989); Hatanaka & Ojima (1981); Smith (1994); Borch et al (1971).…”

“…Compounds possessing this ring system such as aminoquinolines, have wide applications as drugs and pharmaceuticals. Many derivatives of aminoquinolines have been reported as plant resistance factors as topical antiseptic (Albert et al 1955), analgesic (Mouzine et al, 1980) and antimalarials (Lyle et al, 1967). Therefore, considerable efforts have been directed towards the preparation and synthetic manipulation of these molecules.…”