Chem. Sci.
 2023
DOI: 10.1039/d3sc02253f
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The contrasting reactivity of trans- vs. cis-azobenzenes (ArNNAr) with benzynes

Dorian S. Sneddon
1
,
Thomas R. Hoye
2

Abstract: E- vs. Z-azobenzenes engage benzynes in complementary fashion, producing either dihydrophenazine or N-aminocarbazole skeletons, respectively. DFT and experimental mechanistic studies shed light on why.

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