The Copolymer of Allyl Alcohol and 1,3-Butadiene<sup>1</sup>

Marvel, C. S.; Potts, R. M.; King, Charly

doi:10.1021/ja01606a059

Cited by 3 publications

(2 citation statements)

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“…For example, allyl alcohol was shown to inhibit the polymerization of butadiene; therefore, one must prepare such a copolymer indirectly (229). For example, allyl alcohol was shown to inhibit the polymerization of butadiene; therefore, one must prepare such a copolymer indirectly (229).…”

Section: Ishibition a S D Acceleratiosmentioning

confidence: 99%

“…For example, allyl alcohol was shown to inhibit the polymerization of butadiene; therefore, one must prepare such a copolymer indirectly (229). Along the same line, Griffin, Esteve, and Laible found that a small percentage of added allyl alcohol (4 per cent) greatly inhibited the polymerization of triallyl phosphate, so that double the quantity of peroxide initiator was required to complete the polymerization (167).…”

Section: Inhibition and Accelerationmentioning

confidence: 99%

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Allyl Polymerizations

Laible¹

1958

Chem. Rev.

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Section: Ishibition a S D Acceleratiosmentioning

confidence: 99%

Section: Inhibition and Accelerationmentioning

confidence: 99%

Allyl Polymerizations

Laible¹

1958

Chem. Rev.

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The chemical modification of polymers for analytical purposes

Harwood

1968

Angew. Makromol. Chem.

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When it is possible to convert one polymer quantitatively into another, the derived polymer can sometimes be studied to obtain information about the original polymer. In other instances, the derived polymer can serve as a reference material for use in the development of polymer characterization procedures. This paper reviews the use of such techniques in studies on branching and stereoregularity in homopolymers and in studies on sequence distribution in copolymers. The reactions covered include hydrolysis, ammonolysis, alcoholysis, esterification, transesterification and the hydrogenation of polyhalocarbons and unsaturated polyhydrocarbons. In addition, recent studies on cyclization reactions in polymers are surveyed. Such studies can provide information about sequence distribution in copolymers. ZUSAMMENFASSUNG :Derivate von Polymeren, die durch quantitative Umwandlung entstanden sind, konnen in gewissen Fallen dazu benutzt werden, die Eigenschaften des Ausgangspolymeren zu untersuchen. Das Polymerderivat kann auch als Bezugssubstanz bei der Entwicklung von Methoden zur Charakterisierung von Polymeren dienen. I n dieser Arbeit wird uber die Anwendung derartiger Methoden fur Untersuchungen uber die Verzweigung und Stereoregularitiit von Homopolymeren und die Sequenzverteilung von Copolymeren berichtet. Es werden verschiedene Reaktionen beschrieben, darunter Hydrolyse, Ammonolyse, Alkoholpse, Veresterung, Umesterung und die Hydrierung von Polyhalogenkohlenwasserstoffen und ungesatt,igten Polykohlenwasserstoffen. Weiterhin wird ein uberblick uber neuere Ringschlufireaktionen an Polymeren gegeben. Derartige Reaktionen konnen fur Untersuchungen der Sequenzverteilung von Copolymeren von Wichtigkeit sein.

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