The copolymerisation of methyl and ethyl methacrylate in supercritical carbon dioxide

Giles, Matthew R.; Hay, J. N.; Howdle, Steven M.

doi:10.1002/1521-3927(20001001)21:15<1019::aid-marc1019>3.0.co;2-m

Cited by 20 publications

(1 citation statement)

References 14 publications

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“…7 Since the first reported 8 successful radical dispersion polymerisations in scCO 2 , many vinyl monomers have been polymerised in this reaction medium. 9–18…”

Section: Introductionmentioning

confidence: 99%

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO₂

et al. 2021

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“…7 Since the first reported 8 successful radical dispersion polymerisations in scCO 2 , many vinyl monomers have been polymerised in this reaction medium. 9–18…”

Section: Introductionmentioning

confidence: 99%

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO₂

et al. 2021

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Polymerization in Supercritical Carbon Dioxide

Beginn

2010

Handbook of Green Chemistry

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The sections in this article are General Aspects Introduction and Scope Supercritical Fluids Solubility of Macromolecules in sc CO 2 Stabilizer Design for Dispersion Polymerizations Limitations of Polymer Preparation in sc CO 2 Polymerization in sc CO 2 Radical Polymerization in sc CO 2 Side‐chain Fluoropolymers Fluoroolefin Polymers Poly(Methyl Methacrylate) Polystyrene Other Vinyl Monomers Metal‐catalyzed Polymerizations Polyolefins Other Metal‐catalyzed Polymerizations Ionic Chain Polymerizations Cationic Polymerizations Coordinative Anionic Polymerization Conclusion

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Synthesis of polydimethylsiloxane‐block‐polystyrene‐block‐polydimethylsiloxane via polysiloxane‐based macroinitiator in supercritical CO₂

Akgün

Deniz

Baran

et al. 2004

Polymer International

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Polydimethylsiloxane-block-polystyrene-block-polydimethylsiloxane (PDMS-b-PS-b-PDMS)was synthesized by the radical polymerization of styrene using a polydimethylsiloxane-based macroazoinitiator (PDMS MAI) in supercritical CO 2 . PDMS MAI was synthesized by reacting hydroxyterminated PDMS and 4,4 -azobis(4-cyanopentanoyl chloride) (ACPC) having a thermodegradable azo-linkage at room temperature. The polymerization of styrene initiated by PDMS MAI was investigated in a batch system using supercritical CO 2 as the reaction medium. PDMS MAI was found to behave as a polyazoinitiator for radical block copolymerization of styrene, but not as a surfactant. The response surface methodology was used to design the experiments. The parameters used were pressure, temperature, PDMS MAI concentration and reaction time. These parameters were investigated at three levels (−1, 0 and 1). The dependent variable was taken as the polymerization yield of styrene. PDMS MAI and PDMS-b-PSb-PDMS copolymers obtained were characterized by proton nuclear magnetic resonance and infrared spectroscopy. The number-and weight-average molecular weights of block copolymers were determined by gel permeation chromatography.

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The copolymerisation of methyl and ethyl methacrylate in supercritical carbon dioxide

Cited by 20 publications

References 14 publications

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO₂

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO₂

Polymerization in Supercritical Carbon Dioxide

Synthesis of polydimethylsiloxane‐block‐polystyrene‐block‐polydimethylsiloxane via polysiloxane‐based macroinitiator in supercritical CO₂

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The copolymerisation of methyl and ethyl methacrylate in supercritical carbon dioxide

Cited by 20 publications

References 14 publications

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO2

Polymerization in Supercritical Carbon Dioxide

Synthesis of polydimethylsiloxane‐block‐polystyrene‐block‐polydimethylsiloxane via polysiloxane‐based macroinitiator in supercritical CO2

Contact Info

Product

Resources

About

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO₂

Influence of structure and solubility of chain transfer agents on the RAFT control of dispersion polymerisation in scCO₂

Synthesis of polydimethylsiloxane‐block‐polystyrene‐block‐polydimethylsiloxane via polysiloxane‐based macroinitiator in supercritical CO₂