The crystal and molecular structure of di-μ-chloro-bis[thioacetamide(chloro)cadmium(II)]

Reversible recrystallization process of copper and silver thioacetamide–halide coordination polymers and their basic building blocks

“…Additionally, the hydrogen bond interactions of amide groups play an essential role in proteins and polyamides; 34,35 however, they have received little attention in the field of supramolecular chemistry. 36 Surprisingly a recent revision in the CSD shows just three hits referring to CPs with aliphatic thioamides (Cd II , 37 Ni II , 38 and Cu I (ref. 39)).…”

Acetic Acid-Assisted Solution Process for Growth of Complex Copper Sulfide Microtubes Constructed by Hexagonal Nanoflakes

“…In fact, there are lone pair electrons on nitrogen and sulfur atoms of each TAA, which provides the possibility that TAA can combine with the Cu 2+ ions to form a Cu 2+ −TAA complex as in the case of the transition metal ions M 2+ (M = Cu, Cd, Zn, Ni, etc. ). , It can be inferred that the complex possibly has a composition of [Cu−(TAA) 2 ]Cl 2 . The thermal stability of the complex was examined by TGA.…”

Halide-bridged polymers of divalent metals with donor ligands – structures and properties

“…The polymer has the composition [{Cu(-Cl) 2 (hmpa) 2 }{Pd(-Cl) 2 } 2 ] ∞ and is built up from edge-sharing pseudo-octahedral Cu(II) and squareplanar Pd(II) cations. [180], (b) imidazole [181], and (c) methylurea [182]. …”

“…Neutral double chains are obtained with the donor ligands thioacetamide [180], imidazole [181] and monomethylurea [182]. Fig.…”