1973
DOI: 10.1107/s0567740873006795
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The crystal structure of Bi2(MoO4)3

Abstract: A, and 0.003 rad (0.2 °) in the final cycle, the r.m.s, average of the translations of the rigid bodies totaled over all the rings is 0.082 A. The same average over the rotations is 0.029 rad (1.7°). A second measurement of the similarily between the observed and calculated structures is the r.m.s, displacement of the atoms. Since the phenyl rings were refined as rigid bodies, the comparison must be made between the final atomic coordinates of the calculated structure and the idealized coordinates based on Dal… Show more

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Cited by 128 publications
(46 citation statements)
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“…The observed XRD reflections of the samples coincide with the reference data reported by the other authors, for instance [13][14][15] and can be ascribed to the following structures: α-Bi 2 Mo 3 O 12 (2/3) and β-Bi 2 Mo 2 O 9 (1/1) phases to the monoclinic structure and γ-Bi 2 MoO 6 (2/1) phase to the orthorhombic structure. A little amount of the "polluting" β-phase, detected by the d hkl = 3.227 and 2.821 Å reflections, was found in sample 2/1 (γ-phase).…”
Section: Crystallographic Structure and Phase Compositionsupporting
confidence: 74%
See 1 more Smart Citation
“…The observed XRD reflections of the samples coincide with the reference data reported by the other authors, for instance [13][14][15] and can be ascribed to the following structures: α-Bi 2 Mo 3 O 12 (2/3) and β-Bi 2 Mo 2 O 9 (1/1) phases to the monoclinic structure and γ-Bi 2 MoO 6 (2/1) phase to the orthorhombic structure. A little amount of the "polluting" β-phase, detected by the d hkl = 3.227 and 2.821 Å reflections, was found in sample 2/1 (γ-phase).…”
Section: Crystallographic Structure and Phase Compositionsupporting
confidence: 74%
“…This is a reason why the activation energies increase and conductivities decrease at high temperatures. In both observed regions, the high- est electrical conductivity was found to be in the case of the γ-phase (sample 2/1) with the orthorhombic structure and the highest theoretical density, ρ theor = 8.26-8.28 g/cm 3 [13]. The lowest electrical conductivity was observed for the α-phase (sample 2/3) with the monoclinic structure and the lowest theoretical density, ρ theor = 6.19-6.26 g/cm 3 [19].…”
Section: Electrical Conductivity and Dielectric Permittivitymentioning
confidence: 91%
“…Among these bismuth molybdates, ␣-Bi 2 Mo 3 O 12 oxide has a deficient oxygen fluorite structure with Mo in MoO 4 tetrahedra and vacancies every three Bi sites [11,12]. These vacancies are in an ordered arrangement at room temperature within the infinite Bi channels and with three different Mo sites, each of which is coordinated by five O atoms.…”
Section: Introductionmentioning
confidence: 99%
“…In hydroxyapatites Y denotes the OH group. The structure of BMO is monoclinic, with the space group P2 1 /c (a = 7.685, b = 11.491, c = 11.929 Å, β = 115.4 o ) [7]. It can be considered as a scheelite structure with ordered cation vacancies.…”
Section: Introductionmentioning
confidence: 99%