The crystal structure of carbonyl(2-oxopyridin-1(2H)-olato-κ ² O,O′)-(diphenylcyclohexylphosphine-κ P)rhodium(I), C₂₄H₂₅NO₃PRh

Abstract

CCDC no.: 1560838The asymmetric unit of the title crystal structure is shown in the figure. Tables 1 and 2 contain details of the measurement method and a list of the atoms including atomic coordinates and displacement parameters. Experimental detailsThe H atoms were placed in geometrically idealized positions and constrained to ride on their parent atoms with

(N-Benzoyl-N-phenylhydroxylaminato)carbonyl(triphenylarsine)rhodium(I)

“…The crystal structure is isotypic with that of [Rh(BPHA)(PPh 3 )(CO)] and shows similar Rh-O and Rh-C bond lengths (2.037/2.089 and 1.809 A ˚, respectively; Leipoldt & Grobler, 1982). The coordination environment in the molecule of [Rh(BPHA)-(AsPh 3 )(CO)] is distorted square planar, as shown by the small O1-Rh-O2 bite angle of 79.53 (7) , which is similar to the bite angles of related structures with O,O-binding five-membered chelate rings reported in the literature (Elmakki et al, 2017). The C02-Rh-O2 and C02-Rh-O1 angles involving the C02 O02 carbonyl ligand were also found to deviate from ideal values, at 99.31 (9) and 178.39 (10) , respectively, similar to those of related structures (Elmakki et al, 2016).…”

Crystal structure of carbonyl(2-methylquinolin-8-olato-κ2 N,O)(triphenylarsine-κAs)rhodium(I), C29H23AsNO2Rh

“…altering the electronic and steric properties of the ligand resulting in significant changes in the outcome of the catalytic process. These complexes have been studied intensively for potential application in catalytic hydroformylation, hydrogenation, carbonylation, and decarbonylation [8][9][10][11][12][13][14][15][16][17][18][19]. The coordination mode in the title complex is similar to the complexes reported previously [20].…”