The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ2
 N,N′)palladium(II), C14H12Cl2N4Pd

Si, Xiang; Yan, Qiong

doi:10.1515/ncrs-2021-0449

Zeitschrift Für Kristallographie - New Crystal Structures

2022

DOI: 10.1515/ncrs-2021-0449

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The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ² N,N′)palladium(II), C₁₄H₁₂Cl₂N₄Pd

Xiang Si¹,

Qiong Yan²

Abstract: C14H12Cl2N4Pd, monoclinic, P21/c (no. 14), a = 11.990(3) Å, b = 13.027(3) Å, c = 9.730(2) Å, β = 92.163(4)°, V = 1518.7(6) Å3, Z = 4, R gt (F) = 0.0290, wR ref (F 2) = 0.0856, T = 296(2) K. CCDC no.: 2118554

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N,S-Chelating triazole-thioether palladium for the one-pot synthesis of biaryls

Yan

Huang

2022

Aust. J. Chem.

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In this work, for the one-pot two-step coupling reaction of aryl halides with bis(pinacol)diboron, we first applied a phosphorus-free N,S-chelated triazole sulfide palladium-catalyzed system. At the same time, we also carried out careful ligand design to explore the effect of the environment around the coordinating sulfur atom on the reaction. Experiments have shown that the N2-thioether substituted 1,2,3-triazlole palladium is an optimal catalyst The reaction could also reach up to quantitative yield in 4 h with only 1 mol% catalyst. Moreover, some low-activity aryl chlorides can also be coupled with bis(pinacolato)diboron under this catalytic system. We were able to obtain biaryls containing various functional groups in good to excellent yields.

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N,S-Chelating triazole-thioether palladium for the one-pot synthesis of biaryls

Yan

Huang

2022

Aust. J. Chem.

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The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ ² N, N′)palladium(II), C₁₂H₂₀N₂PdCl₂

Lin,

Zhan,

Liang

et al. 2024

Zeitschrift Für Kristallographie - New Crystal Structures

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The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ² N,N′)palladium(II), C₁₄H₁₂Cl₂N₄Pd

Abstract: C14H12Cl2N4Pd, monoclinic, P21/c (no. 14), a = 11.990(3) Å, b = 13.027(3) Å, c = 9.730(2) Å, β = 92.163(4)°, V = 1518.7(6) Å3, Z = 4, R gt (F) = 0.0290, wR ref (F 2) = 0.0856, T = 296(2) K. CCDC no.: 2118554

Cited by 2 publications

References 11 publications

N,S-Chelating triazole-thioether palladium for the one-pot synthesis of biaryls

N,S-Chelating triazole-thioether palladium for the one-pot synthesis of biaryls

The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ ² N, N′)palladium(II), C₁₂H₂₀N₂PdCl₂

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The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ2 N,N′)palladium(II), C14H12Cl2N4Pd

Abstract: C14H12Cl2N4Pd, monoclinic, P21/c (no. 14), a = 11.990(3) Å, b = 13.027(3) Å, c = 9.730(2) Å, β = 92.163(4)°, V = 1518.7(6) Å3, Z = 4, R gt (F) = 0.0290, wR ref (F 2) = 0.0856, T = 296(2) K. CCDC no.: 2118554

Cited by 2 publications

References 11 publications

N,S-Chelating triazole-thioether palladium for the one-pot synthesis of biaryls

N,S-Chelating triazole-thioether palladium for the one-pot synthesis of biaryls

The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ 2 N, N′)palladium(II), C12H20N2PdCl2

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The crystal structure of dichlorido-(2-((4-phenyl-2H-1,2,3-triazol-2-yl)methyl)pyridine-κ² N,N′)palladium(II), C₁₄H₁₂Cl₂N₄Pd

The crystal structure of dichlorido-(N-isopropyl-N-(pyridin-2-ylmethyl)propan-2-amine-κ ² N, N′)palladium(II), C₁₂H₂₀N₂PdCl₂