The crystal structure of tris(1-ethylimidazole-κ¹ N)-(sulfato-κ² O,O′)vanadium(IV), C₁₅H₂₄N₆O₅SV

Abstract

<jats:title>Abstract</jats:title><jats:p>C<jats:sub>15</jats:sub>H<jats:sub>24</jats:sub>N<jats:sub>6</jats:sub>O<jats:sub>5</jats:sub>SV, monoclinic, <jats:italic>P</jats:italic>2<jats:sub>1</jats:sub>/<jats:italic>c</jats:italic> (no. 14), <jats:italic>a</jats:italic> = 16.0059 Å, <jats:italic>b</jats:italic> = 9.1008 Å, <jats:italic>c</jats:italic> = 14.2686 Å, <jats:italic>β</jats:italic> = 100.352°, <jats:italic>V</jats:italic> = 2044.6(2) Å<jats:sup>3</jats:sup>, <jats:italic>Z</jats:italic> = 4, <jats:italic>R</jats:italic><jats:sub>gt</jats:sub>(<jats:italic>F</jats:italic>) = 0.0400, <jats:italic>wR</jats:italic><jats:sub>ref</jats:sub>(<jats:italic>F</jats:italic><jats:sup>2</jats:sup>) = 0.0852, <jats:italic>T</jats:italic> = 173(2) K.</jats:p>

The crystal structure of tetrakis(1-methylimidazole-κ1 N)-oxido-(sulfato-κ1 O)vanadium(IV), C16H24N8O5SV

“…The title compound reveals octahedral environment around the vanadium atom, which is in agreement with previous reports [5,12]. The central vanadium atom is bonded to one terminal oxygen, one oxygen from sulfate and four nitrogen atoms from four different 1-methylimidazole (see the figure).…”

“…It is very meaningful to synthesize complexes based on vanadium. VOSO4 is often used as precursor for their solubility in many organic solvents [11,12]. Here, we prepared a vanadium complex by the one step solvothermal technique.…”