2024
DOI: 10.26434/chemrxiv-2024-gjvnc
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The Cyanoketene Anion [NC3O]-

Felix Krischer,
Varre S. V. S. N. Swamy,
Kai-Stephan Feichtner
et al.

Abstract: Cumulenes and heterocumulenes with three or more cumulative multiple bonds are usually reactive species, that serve as valuable building blocks to more complex molecules but tend to isomerize or cyclize and therefore are difficult to isolate. Until to date, numerous (hetero)cumulenes have been detected in the interstellar medium and are assumed to be important intermediates in prebiotic chemistry, in particular when containing nitrogen and oxygen functionalities. Using a mild ligand exchange reaction at carbon… Show more

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