The cyclopolymerization of some nitrogen-containing diepoxy compounds

Sorokin, M.F.; Shode, L. G.; Dobrovinskii, L.A.; Onosov, G.V.

doi:10.1016/0032-3950(72)90212-2

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Study Of Curing Kinetics Using Torsion Pendulum Methods1

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2003

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“…At later stages in the process, however, there is an inversion, and the crosslinking density is higher at a temperature of 160°C. We may assume that this result comes about because of the capacity of EKhD resin to self-polymerise [29,30] at high temperatures under the influence of the tertiary aminogroups that enter into its structure. The phenol groups in the curing resin may accelerate a side reaction, lowering the effective level of cross-linking for the given composition, and consequently also its heat resistance.…”

Section: Study Of Curing Kinetics Using Torsion Pendulum Methodsmentioning

confidence: 99%

Prepregs with Long Service Life. 2. Rheokinetic Selection of Industrial Types of Epoxy Resins and Curing Agents

Smirnov

Kruzhkova

Shatskaia³

et al. 2003

International Polymer Science and Technology

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Section: Study Of Curing Kinetics Using Torsion Pendulum Methodsmentioning

confidence: 99%

Prepregs with Long Service Life. 2. Rheokinetic Selection of Industrial Types of Epoxy Resins and Curing Agents

Smirnov

Kruzhkova

Shatskaia³

et al. 2003

International Polymer Science and Technology

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Low‐temperature thermal decomposition of an epoxy resin

Grayson¹,

Wolf²

1984

J. Polym. Sci. Polym. Chem. Ed.

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The thermal decomposition of the epoxy resin system, MY720 (70 wt % tetraglycidyl diaminodiphenyl methane), cured with Eporal (diamino diphenyl sulfone), was investigated at 125–215°C. The primary decomposition product was propenal. Several other aldehydes were observed; however, they are formed during cure and are not thermal decomposition products. The apparent activation energy for the production of propenal was 67 kJ/mol (16 kcal/mol). Possible mechanisms for the source of this compound are discussed.

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The cyclopolymerization of some nitrogen-containing diepoxy compounds

Cited by 2 publications

References 6 publications

Prepregs with Long Service Life. 2. Rheokinetic Selection of Industrial Types of Epoxy Resins and Curing Agents

Prepregs with Long Service Life. 2. Rheokinetic Selection of Industrial Types of Epoxy Resins and Curing Agents

Low‐temperature thermal decomposition of an epoxy resin

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