The Cyclopropyl Group in Studies of Enzyme-Catalysed Reactions

Suckling, Colin J.

doi:10.1007/978-94-009-0929-8_13

Strain and Its Implications in Organic Chemistry 1989

DOI: 10.1007/978-94-009-0929-8_13

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The Cyclopropyl Group in Studies of Enzyme-Catalysed Reactions

Colin J. Suckling

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1992

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A New Versatile Synthesis of Ring‐Substituted 2‐Cyclopropylglycines and Related Amino Acids

Wessjohann

Krass

et al. 1992

Chem. Ber.

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Alkyl 2-chloro-2-cyclopropylideneacetates 2 serve as universal starting materials for a new general synthesis of cyclopropylglycines by a simple three-to four-step methodology. 1,4-Addition of nucleophiles, substitution with azide ion, and mild catalytic deprotection lead to a variety of salt-free cyclopropyl-substituted amino acids in good yields, including the natural products 2-( 1-methylcyclopropyl)glycine (4) and cleonin (5).

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A New Versatile Synthesis of Ring‐Substituted 2‐Cyclopropylglycines and Related Amino Acids

Wessjohann

Krass

et al. 1992

Chem. Ber.

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The Cyclopropyl Group in Studies of Enzyme-Catalysed Reactions

Cited by 1 publication

References 61 publications

A New Versatile Synthesis of Ring‐Substituted 2‐Cyclopropylglycines and Related Amino Acids

A New Versatile Synthesis of Ring‐Substituted 2‐Cyclopropylglycines and Related Amino Acids

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