The D′ → A′ transition in Cl2

Guo, Baochuan; Chakraborty, Dilip K.; Tellinghuisen, Joel

doi:10.1016/0022-2852(88)90223-8

Cited by 40 publications

(29 citation statements)

References 26 publications

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“…5. This behavior is consistent with the expected approach to Hund's case (a) for the lighter halogens, as noted previously for Cl 2 (24,25). With increasing v, the rotational constants for the A state tail off from their counterparts for AЈ, while those for B increase slightly.…”

Section: Potential Curves and Derived Propertiessupporting

confidence: 91%

TheA(3Π1) State of ClF

Алексеев

Setser

Tellinghuisen

1999

Journal of Molecular Spectroscopy

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Section: Potential Curves and Derived Propertiessupporting

confidence: 91%

TheA(3Π1) State of ClF

Алексеев

Setser

Tellinghuisen

1999

Journal of Molecular Spectroscopy

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“…It is further noteworthy that the Cl 2 transient absorption spectrum reported in the same of experiments. The same situation occurred for I 2 (5); but in that case the source was a CW nozzle, and the spectra paper by Briggs and Norrish has also been reassigned convincingly to the D R A transition (34)(35)(36). were much colder rotationally as well.…”

Section: Mechanistic Considerationsmentioning

confidence: 80%

Spectroscopy of Metastable Species in a Free-Jet Expansion: TheD′ ← A′ Transition in Br2

Marter

Hwang

et al. 1996

Journal of Molecular Spectroscopy

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The A2 u ( 3 P) state of Br 2 is observed in free-jet expansions of UV-photolyzed BBr 3 /Ar mixtures and of electrically discharged Br 2 /Ar mixtures. Laser excitation spectra are recorded for the D2 g ( 3 P 2 ) R A transition, providing the first information about £ Å 0 in the A state. Thirty-one £ 0 0Љ bands spanning £ Å 23-47 are rotationally analyzed. The new results are combined with existing emission spectroscopic data for £ Å 0-6 and £Љ Å 5-21 (a total of 2940 assignments) to provide spectroscopic parameters which should be valid for £Љ Å 0-21 and £ Å 0-50.

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“…Emission spectra were produced and recorded using procedures very much like those described in other recent studies from Vanderbilt (14,17,26). The source was a Tesla discharge, operated in a 7-mm-OD silica tube having a silica window, viewed end-on (27).…”

Section: Methodsmentioning

confidence: 99%

“…The emission spectra are typically highly congested, making interpretation difficult. The use of single-isotopomer sources has been the key to success in a number of cases (16,17). In addition, it has been possible to get around the ⌬⍀ ϭ 0 limitation on the multiple-resonance techniques in ICl (9,18) and Cl 2 (19), where perturbative interactions yield access to the ⍀ ϭ 2 states, and in I 2 (20), where collisional transfer does the same.…”

Section: Introductionmentioning

confidence: 99%