Extensive 7-y coincidence measurements have been made on y rays accompanying the fl-decay of 2t4Bi using a conventional GeGe coincidence spectrometer. A total of 33 new 7 transitions among levels of 214po have been established. Twenty-three previously reported but unplaced transitions have now been assigned in the level scheme. In addition to confirming 56 previously proposed levels, four new levels are established at 1015.05, 1712.98, 3003.5 and 3160.5 keV. Directional correlation measurements have been made on six weak cascades which have the first excited state in common. Mixing ratios have been deduced for the transitions concerned.