The/J-decays of 99y and 99Zr have been investigated with the two recoil fission product separators JOSEF and LOHENGRIN. Half-lives of 1.51_+0.08s and 2.1_+0.1 s respectively, have been determined. A/J-decaying isomeric state has been observed in 99y. 99 99The level schemes of 4oZr59 and 4~Nb58 have been established from ),-ray spectroscopy. Absolute 7-intensities have been obtained by means of two independent techniques. Halflives of 293 _+ 10 ns for the 251.9 keV state and 10.2 • 1.5 ns for the 614.0 or 667.2 keV level in 99Zr have been measured through delayed /3,7-and 7,?,-coincidence experiments.Values for the spins and parities of the low lying levels in 99Zr are proposed in accordance with the systematics of lighter odd Zr isotopes. Spins and partities are assigned to some levels in 99Nb from 7,7-angular correlation measurements. In this nucleus there is evidence for three-particle configurations of some excited states, where the odd proton is coupled to two neutrons which are in different orbits.