Monodisperse samples of magnetite nanoparticles in the size range of 5-13nm, were prepared by solvothermal synthesis and coprecipitation method. Obtained nanoparticles were characterized by different measurement techniques: X-ray diffraction analysis, transmission electron microscopy, selected area electron diffraction measurement, and Fourier transform infra-red spectroscopy. Measurements confirmed that the utilized synthesis methods are able to produce size and shape-controlled nanoparticles of a high-quality, that is of the technological importance. The results of the performed study represent the first stage in preparation of the Fe 3 O 4 nanoparticles as an additive to concrete, which will be used for the construction of the special military facilities where it is necessary to provide a protection against γ-ray radiation.