2009
DOI: 10.1007/978-3-642-01973-9_26
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The Design of Tris(o-phenylenedioxy)cyclo-trisphosphazene (TPP) Derivatives and Analogs toward Multifunctional Zeolite Use

Abstract: Abstract. Taking tris(o-phenylenedioxy)cyclotrisphosphazene (TPP) as template, series of derivatives and analogs were designed with the aim to investigate the structural features of organic zeolite (OZ) and their potential applications. On the basis of DFT-PBE0/6-31G** quantum calculation, the results show a tight dependence of the electron donor (E-D) of the entire molecule on that of the side group and bridge. It was found that extending the side fragment with a phenyl ring and substituting CH/N, or tetrathi… Show more

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