The destruction chemistry of organophosphorus compounds in flames—I: quantitative determination of final phosphorus-containing species in hydrogen-oxygen flames

Kinetic study of the combustion of organophosphorus compounds

“…Addition of trimethylphosphate (TMP) to *Current address: DCPR-CNRS, 1 rue Grandville, 54000 Nancy, France. a H 2 /O 2 flame [14,15] and a CH 4 /O 2 flame [4] was also reported by Korobeinichev et al, with a quantitative determination of the final phosphorus species [4,15,16].…”

Formation and consumption of NO in H2+O2+N2 flames doped with NO or NH3 at atmospheric pressure

“…The mass spectrometer was equipped with improved ion source with a narrow spread of electron energies (±0.25 eV), which corresponds to the thermal scattering of electron energy (approximately 2 kT, where k is Boltzmann constant and T is cathode temperature) [31]. This allowed operating at low ionization energies, which are close to the ionization potentials of the atoms, radicals and molecules.…”

Chemical Transformations in Inhibited Flames over Range of Stoichiometry

“…It is noteworthy that Korobeinichev and co-authors (Korobeinichev et al, 1999d) measured concentration profiles of phosphorus oxides and acids PO, PO 2 , HOPO, HOPO 2 , and (HO) 3 PO in the flame that are the key flame species responsible for H and OH catalytic recombination. In the same work the authors demonstrated that the same chemical processes are responsible for both promotion and inhibition.…”