Pure oxygen demand is continuously increasing worldwide due to wide applications including medical and industrial. Pressure swing adsorption (PSA) is one of the promising techniques to separate O 2 from atmospheric air. The porous solid adsorbent is a key element in the PSA to trap nitrogen (N 2 ) and release O 2 . Several adsorbents including low silica X (LSX), zeolite 5A, ionexchanged LSX (Li-LSX, AgLi-LSX, Ca-LSX), Engelhard titanosilicate (Na-ETS-10, Ag-ETS-10), and SSZ-13 have been investigated for adsorption of N 2 from the air. This review article is a summarization of recent research work published on O 2 separation using different porous adsorbents via PSA. This review also emphasizes on the best porous sorbent for purification of O 2 by sorption of N 2 and Ar. The adsorption capacities with experimental conditions are also rigorously discussed. The review also proposed future trends and prospects for O 2 separation. This review will be helpful to choose remarkable adsorbent for the generation pure O 2 .