“…From theory, it has been established that nitrogen-induced band gap reduction in these materials occurs in a similar way to that in low indium content InGaAsN [14] and it exhibits some interesting phenomena, such as, weaker interaction between the nitrogen level and the conduction band as compared to that in low In content InGaAsN [10] and a change in nitrogen bonding configuration upon annealing [12]. Furthermore, for this alloy there are many applications within the technologically important mid-infrared (2-5 µm) spectral range [15,16] including; laser based remote sensing of pollutant and greenhouse gases, thermal imaging, biomedical analysis and infrared countermeasures for security, as well as in thermo-photovoltaic devices [17]. Although midinfrared LEDs, lasers and photodetectors have been demonstrated [18][19][20][21], the fabrication of efficient and cost-effective light sources and detectors is challenging because of the unfavorable imbalance in the density of states (DOS) due to the light electron effective mass in InAs [22,23].…”