SYNOPSISResults are given for dielectric constant and loss factor of some cellulosic materials of different fine structure free of and contaminated with water-soluble inorganic salts in the frequency range 0.1-100 kc/s and at temperatures 283.15-333.15 K. The analysis of the results reveals that the dielectric dispersion and loss peak found before with medicated cotton and viscose rayon, of ash contents of 0.3 and 1.4% respectively, disappear when these fibers have been "cleaned up" from inorganic impurities by acid washes. These anomalous dielectric behaviours reappear again with "cellulose-inorganic salts" admixtures. Based on these findings, it has been concluded that the secondary relaxation process observed in the low-frequency region 0.1-1 kc/s with cellulosic materials contaminated with inorganic impurities is not intrinsic but extrinsic in nature due to the displacement of ions adsorbed in the inner surfaces of such interstitial conduction system.