2009
DOI: 10.1016/j.jpowsour.2008.10.022
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The diffusion overpotential increase and appearance of overlapping arcs on the Nyquist plots in the low humidity temperature test conditions of polymer electrolyte fuel cell

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Cited by 28 publications
(13 citation statements)
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“…Liquid water in MEAs arises from condensed humidified vapor and as a product of oxygen reduction, some of which is necessary for maintaining the ionic conductivity of the membrane and catalyst layer (CL). Excess water may occlude active sites for electrochemical reaction and affect the gas permeability [6][7][8]. Most water is transported out of the cathode CL and accumulates at the interface between the CL and GDL before draining from the MEA through the GDL by capillary action [9].…”
Section: Introductionmentioning
confidence: 99%
“…Liquid water in MEAs arises from condensed humidified vapor and as a product of oxygen reduction, some of which is necessary for maintaining the ionic conductivity of the membrane and catalyst layer (CL). Excess water may occlude active sites for electrochemical reaction and affect the gas permeability [6][7][8]. Most water is transported out of the cathode CL and accumulates at the interface between the CL and GDL before draining from the MEA through the GDL by capillary action [9].…”
Section: Introductionmentioning
confidence: 99%
“…In the Nyquist plots, g-CL/g-GDL presented a pronounced but small arc at low frequencies, suggesting that g-CL/g-GDL exhibited a lower gas-diffusion resistance. 32 For an accurate and specific comparison, the Nyquist plots were fitted and the results are displayed in Figure S7b. 33 It was shown that g-CL/g-GDL possessed a lower gasdiffusion resistance of 0.07 Ω cm 2 , which was significantly smaller than that of the commercial GDE (0.21 Ω cm 2 ).…”
Section: ■ Results and Discussionmentioning
confidence: 99%
“…Resulting from more electrochemical active sites, the diffusion length of oxygen is shorter, which reduces the mass transport polarization. 34 …”
Section: Resultsmentioning
confidence: 99%
“…Resulting from more electrochemical active sites, the diffusion length of oxygen is shorter, which reduces the mass transport polarization. 34 For further study water transport process inside fuel cell, water transport was tested as shown in Table 4. The smallest anode water content is mainly due to lack of back diffusion at inlet of fuel cell resulting from lowest gas humidity.…”
Section: Effect Of Surface Evaporation Rate On Humidication Functionmentioning
confidence: 99%