THE DISTRIBUTION OF Pu(VI) AND Pu(III) IN THENOYL-TRIFLUOROACETONE-BEZENE- NITRIC ACID MIXTURES

Heisig, D.L.; Hicks, T.E.

doi:10.2172/4352603

Search citation statements

Order By: Relevance

Paper Sections

Select...

Results2

Citation Types

Supporting

Mentioning

Contrasting

Year Published

1983

Publication Types

Select...

Article1

Relationship

Self Cite0

Independent1

Authors

Journals

Cited by 1 publication

(2 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The extraction constant determined from data in Table 1 compares quite favorably with extraction constants available in the literature for the extraction of plutonium(IV) by TTA [5][6][7][8][9][10]. PoSKANZER and FoRE-MAN [8] reviewed extraction of most of the metallic elements by TTA.…”

Section: Resultssupporting

confidence: 51%

“…PoSKANZER and FoRE-MAN [8] reviewed extraction of most of the metallic elements by TTA. They record the results of CONNICK and REAS [9], HEISIGand HICKS [10], and LATIMER [11] who found values of log/T,^ for Pu(IV) 6.8 from HCIO4 media, 6.3 from HNO3 media, and 6.8 from HCl media, respectively. IRVING and EDGINGTON [12]report log/Tj^ = 6.4 for extraction from HNO3.…”

Section: Resultsmentioning

confidence: 91%

See 1 more Smart Citation

Free Energy, Enthalpy, and Entropy of Plutonium(IV) - Sulfate Complexes

Nash¹,

Cleveland

1983

Radiochimica Acta

View full text Add to dashboard Cite

The compluxation of Pu(IV) by sulfate has been studied (in 1M acid, 2Af ionic strength Perchlorate media) by a TTA (thenoyltrifluoroacetone) extraction procedure. Experiments were performed at 0.0, 10.0, 25.0, and 35.0°C to allow calculation of the enthalpy and entropy of the complexation reactions. From the thermodynamic Parameters and comparison with stability constants determined in a previous study at 2^ acidity and ionic strength, the postulated reactions are

show abstract