Fly ash residues from several sites in which solid municipal refuse is being incinerated for energy production were found to contain excessive amounts of cadmium and/or lead according to an empirical extraction test (0.5 N acetic acid) developed by the Environmental Protection Agency. Samples of associated bottom ashes contained acceptable levels of Cd and Pb, but several were marginal with respect to Pb content. Leaching tests clearly demonstrated that Cd and, to a lesser extent, Pb were mobile in soil when applied in a fly ash matrix. The high chloride content (10-12%), which is characteristic of these ashes, resulted in metal complexation and enhanced Cd and Pb mobility in soil. Normally these elements are relatively immobile in soils when applied as inorganic salts or contained in municipal sewage sludge. Plant uptake of Cd and Pb in a greenhouse test was marked when fly or finely ground bottom ashes were soil applied. Phytotoxicity of fly ash appeared to be associated with the high salt content rather than with a specific metal.