The paper is concerned with the Neumann eigenvalues for second-order Sturm–Liouville difference equations. By analyzing the new discriminant function, we show the interlacing properties between the periodic, antiperiodic, and Neumann eigenvalues. Moreover, when the potential sequence is symmetric and symmetric monotonic, we show the order relation between the first Dirichlet eigenvalue and the second Neumann eigenvalue, and prove that the minimum of the first Neumann eigenvalue gap is attained at the constant potential sequence.