The detonation process of non‐ideal explosives is influenced by the casing of the bomb. Non‐ideal charges in the process of the explosion of live ammunition energy output mechanism and distribution ratio, the impact of the case on the explosion flow field, and other issues cannot be obtained through the existing theoretical analysis and testing techniques to obtain specific values. This paper establishes a “detonation+afterburning” energy output model to characterize the energy release characteristics of non‐ideal charges, using step‐by‐step numerical simulation of the near and middle, and far fields of the explosion, and verify simulation results through experiments, quantitative analysis the case of a type of earth penetrator on the normal particle size (4 μm) and two times the normal particle size (8 μm) of non‐ideal charges of aluminum powder explosion process. The results indicate that the presence of the casing enhances the energy output of aluminum powder with 4 μm by ≈5 %. When the particle size of aluminum powder is doubled, the maximum reaction rate and the peak of the shock wave are merely around 35 % and 75 %, respectively, compared to those of normal particle size. The detonation products, case fragments, and air constitute 49 %, 48 %, and 3 % of the overall explosion energy, respectively. The proportional equation of the conversion between the chemical energy of the explosion and the kinetic energy of the case fragments is obtained. These conclusions can provide data support for the design of non‐ideal charge warheads, lethality assessment, and establishment of engineering protection standards.