1998
DOI: 10.1016/s0014-3057(97)00067-0
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The effect of accelerator/sulphur ratio on the scorch time of epoxidized natural rubber

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Cited by 58 publications
(31 citation statements)
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“…Five accelerators MBT, TMTD, ZDMC, DPG and TBBS were supplied by Bayer. The technical specifications of the rubbers and accelerators were given in our previous paper [3]. Carbon black (330), silica (vulkasil-S) and calcium carbonate having a surface area of 70 m2/g, 170 m2/g and 22 m2/g and partical size of 30 nm, 19 nm and 75 nm respectively were chosen as the fillers, with loading ranged from 0 -60 phr.…”
Section: Methodsmentioning
confidence: 99%
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“…Five accelerators MBT, TMTD, ZDMC, DPG and TBBS were supplied by Bayer. The technical specifications of the rubbers and accelerators were given in our previous paper [3]. Carbon black (330), silica (vulkasil-S) and calcium carbonate having a surface area of 70 m2/g, 170 m2/g and 22 m2/g and partical size of 30 nm, 19 nm and 75 nm respectively were chosen as the fillers, with loading ranged from 0 -60 phr.…”
Section: Methodsmentioning
confidence: 99%
“…The concentrations of sulphur and the accelerators were varied to ascertain different vulcanization systems i.e. CV, semi-EV and EV [3]. The compound was then kept in a close container maintained at 23 i 3°C for 24 h before testing.…”
Section: Methodsmentioning
confidence: 99%
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“…This phenomenon is caused by the activation effect of the polar epoxidized groups on double bonds, which also made unfilled ETPI 18 mix have shorter vulcanizate time (t 90 ) [14,15]. With the increase of C 1 , the epoxy groups on ETPI molecular were well distributed, thus making adjacent double bonds more activate and subsequent the unfilled ETPI 18 mix with higher C 1 showed faster curing rate in curing reaction.…”
Section: Resultsmentioning
confidence: 99%
“…In the past, these molecular species have been used as polymer catalysts, [5] fungicides, [6] bactericides, [7,8] or molecular markers for urban environment [9] and present a good molecular stability in solution at room temperature and under visible light. However, after preparing an aqueous solution of indoline-2-thione and exposing this solution to solar radiation, we have found that this compound follows a typical behavior of photochemical actinometer of ultraviolet radiation; that is, these compounds present a simple isosbestic spectral pattern after ultraviolet irradiation or sunlight exposition.…”
Section: Introductionmentioning
confidence: 99%