Diamond is not an unfamiliar material for most people as it is being widely used in jewelry over the past several centuries. Besides being metastable and having a shiny appearance, diamond has the highest mineral hardness and thermal conductivity among natural materials while posessesing extraordinary properties among ultra-wide bandgap semiconductors. Compared with traditional semiconductors, such as Si, GaAs, SiC, and so on, diamond has superior carrier mobility, good optical transparency, and high radiation hardness. As a result, radiation detector applications in high-energy physics experiments began to exploit natural diamond materials from as early as in the middle of the last century. However, the highly variable and uncontrollable defect content and concentration of impurities in natural diamonds constrain the advanced and reliable application of diamond electronic devices. In recent years, the development of diamond synthesis techniques via chemical vapor deposition (CVD) has led to investigations into diamond electronic applications, as large-area (centimeter scale) production of single-crystal diamond can be realized, and the impurity concentration can be controlled. Diamond radiation detectors therefore represent one of the research projects that underwent some decades of investigation and are still being under study. In this chapter, we summarize the detection mechanisms in two different types of diamond detectors: 1) diamond photoconductors and 2) Schottky barrier photodiodes, which depend strongly on the contact properties between the electrode materials and diamond surface. Meanwhile, the main features of diamond detectors, like responsivity, quantum efficiency, charge collection efficiency, charge collection distance, and others, are introduced and discussed. The remarkable properties of diamond promise several opportunities in a diverse range of application fields, whereas the daunting technical challenges, such as relating to size, doping, and manufacturing scalability, are still in the way of high technology commercialization, especially in electronics. Nevertheless, with new developments in materials synthesis, and research and practical applications, the outlook for diamond is exciting.