Abstract. Successful retardation or arrest of fatigue crack is observed in self-healing epoxy composite containing dual encapsulated healant, i.e. two types of microcapsules that respectively include epoxy prepolymer and mercaptan/tertiary amine hardener. Fast curing of the released healing agent from the broken capsules leads to rapid development of its bonding strength and fracture toughness at room temperature. It is found that the effects of microcapsules induced-toughening, hydrodynamic pressure crack tip shielding, polymeric wedge and adhesive bonding of the healing agent are responsible for the extension of fatigue life. Depending on the applied stress intensity range, !KI, and the competition between polymerization kinetics of the healing agent and crack growth rate, the above mechanisms exert different influences on crack retardation. The results might serve as a reference for further improving the performance of the healant system under fatigue circumstances. Vol.5, No.1 (2011) 47-59 Available online at www.expresspolymlett.com DOI: 10.3144/expresspolymlett.2011.6 * Corresponding author, e-mail: ceszmq@mail.sysu.edu.cn © BME-PT responding to propagating fatigue cracks by autonomic processes that led to higher endurance limit and life extension, or even complete arrest of cracking [5][6][7][8], in addition to the ability to repair the cracks generated by monotonic fracture [9]. The degree of fatigue life extension was found to be dependent on the relative magnitude of mechanical kinetics of crack propagation and chemical kinetics of healing. In our previous work [12], the epoxy/mercaptan/ tertiary amine healing system proved to be able to suppress and rehabilitate fatigue crack in epoxy materials via manual infiltration. Effect of adhesive curing process on fatigue crack propagation was studied in detail. As a continuation of our project, the present paper is focused on self-healing of fatigue crack in epoxy composites containing dual encapsulated healant, i.e. two types of microcapsules that respectively include epoxy prepolymer as the polymerizable component and mercaptan/tertiary amine catalyst as the hardener. The knowledge might provide deeper understanding of the healant for future application.
Keywords: smart polymers, fracture and fatigue, self-healing, epoxy eXPRESS Polymer Letters
Experimental 2.1. Materials and specimen preparationThe encapsulated healing agent, poly(melamineformaldehyde)-walled capsules containing epoxy and its hardener, was made according to the methods described elsewhere [13]. The epoxy-loaded microcapsules hold a 1:1 weight ratio mixture of diglycidyl ether of bisphenol A (EPON 828, Hexion Specialty Chemicals, Columbus, USA) and diglycidyl ether of resorcin (J-80, Wuxi Resin Factory of Bluestar New Chemical Materials Co., Ltd., Jiangsu, China), while the hardener-loaded microcapsules include pentaerythritol tetrakis (3-mercaptopropionate) (PMP, Fluka Chemie AG, Buchs, Switzerland) and 2,4,6-tris(dimethylaminomethyl) phenol (DMP-30, Shanghai Medical Group Reagent C...