We report on a study of the optical properties of undoped AlN/GaN superlattices by means of spectroscopic ellipsometry and photo-and cathodoluminescence. The effect of well and barrier thicknesses on the superlattice transition energies has been studied. Model calculations of the SL miniband structure are performed to compare theoretical predictions with the experimentally determined values of the transition energies.1 Introduction AlGaN/GaN heterostructures have recently attracted considerable attention due to their potential applications for high power transistors and ultraviolet laser diodes. AlGaN/GaN and AlN/GaN superlattices (SLs) are very attractive for strain management, dislocation reduction, p-contacts and also infrared intersubband detectors. However, the fabrication of such heterostructures with high AlN molar fraction, needed for achieving high sheet carrier density, is hindered by the crack formation due to the large built-in strain [1]. Recently, a matal-organic vapor phase epitaxy growth of crack-free AlN on GaN and its application to high mobility AlN/GaN SLs has been demonstrated [2]. While the electrical properties of AlN/GaN SLs have been extensively studied [1,3,4], little is known about their emission properties [5]. In addition no results on the absorption and reflectance of such SLs have been reported.In the present work we report on an ellipsometry study and investigation of the emission properties of undoped AlN/GaN SLs with different well and barrier thicknesses. Photoluminescence (PL) and chathodoluminescence (CL) at low and room temperature (RT), and RT spectroscopic ellipsometry (SE) in the near-infrared-visible-ultra violet range were employed.