The influence of 47 materials on the tenacity of cupric oxide on a cellulose acetate surface has been determined. From these screening tests, seven of the most promising stickers, agar, linseed oil, lime casein, polyvinyl acetate (PVA), coumarone resin, rubber latex and polyvinyl chloride (PVC) were used as supplements to cupric oxide in a potato blight field trial. Although most of the supplements increased the tenacity of the cupric oxide, little, if any, improved blight control was observed. Linseed oil and rubber latex were also used as supplements in a field trial on tomato foliage and the copper residue level was determined chemically.The effect of varying the supplement concentration of boiled linseed oil, PVA and rubber latex on the tenacity of cupric oxide on cellulose acetate and bean leaves was determined.Sedimentation analysis showed that both boiled linseed oil and rubber latex flocculated the cupric oxide suspension, whilst PVA a t a high concentration increased its dispersibility.Assays in uztro against Allernaria tenuis showed that, of the seven CuO-supplement treatments listed above, PVC and PVA were the only supplements that did not decrease the fungitoxicity of the cupric oxide. The physico-chemical aspects of this inhibition are discussed. It is suggested that PVA, at sufficiently high concentration, should prove to be a suitable sticker for copper fungicides.
6The most effective concentrations were the same for both surfaces.
IntroductionThe value of protective fungicides applied to foliage is largely determined by their ability to resist the weathering action of rain, sun and wind, In recent years there has been a tendency to replace Bordeaux mixture by copper compounds such as the oxide, basic carbonate, and oxychloride and various supplementary materials, termed ' stickers ', have been added to the spray suspensions to increase the adhesion of the fungicide to the leaf surface. The resultant effect is assessed in terms of the tenacity of the fungicide, which is defined' as the ratio of the weight of fungicide residue at a given time to its initial deposit.Fajans & Martin1 investigated the effect of a series of chemicals on the tenacity of cuprous oxide and iodide on artificial surfaces. They found that both oils and those substances which gave insoluble residues improved the tenacity, whilst surface-active agents exerted a deleterious effect. A field experiment showed that supplements which increased the tenacity and uniformity of a cuprous oxide deposit also increased its control of potato blight. Harry2 summarized the literature on the use of stickers with pesticide sprays and concluded from this review and from his own work that few of the materials which increase the tenacity of fungicides in laboratory and field trials improve their control of disease. Garman3 found that bentonite-skim milk, soya-bean oil, and some synthetic resin emulsions increased the tenacity of lead arsenatesulphur sprays on privet and apple leaves, and that in field trials with the first two materials improved b...