The effect of CO on the reaction of (tributyltin)lithium with alkyl and aryl bromides

Synthesis of Benzyltributylstannanes by the Reaction of N-Tosylhydrazones with Bu3SnH

“…More recently, palladium-catalyzed stannylation of benzyl or alkyl halides with distannanes (R 3 SnSnR 3 ) has been developed (Scheme b) . The direct substitution reaction of alkyl halides with trialkylstannyl anion represents a straightforward approach (Scheme c) . In addition, it was reported that the reaction of diazo compounds with Bu 3 SnH gave alkylstannane products through carbene insertion, but the studies were mainly focused on mechanistic aspects of the reaction .…”