The effect of compatibilizer on the co‐continuity and nanoclay dispersion level of tpe nanocomposites based on PP/EPDM

Abstract

The effects of different polypropylene (PP)‐g‐maleic anhydride polymers, used as compatibilizers, on the degree of exfoliation and co‐continuity of PP/ethylene‐propylene‐diene terpolymer (EPDM) thermoplastic elastomer (TPE)/clay nanocomposites were investigated. X‐ray diffraction and transmission electron microscopic micrographs showed that nanocomposites ranged from intercalated structure to a coexistence of intercalated tactoids and exfoliated layers. The observed significant increase in crystallization temperature (∼20°C) could be beneficial for molding applications, because it means faster solidification and shorter cycle time. The rheological characteristic relaxation time of the compatibilizer correlated with the dispersion level in the nanocomposites. Solvent extraction and gravimetry measurements of continuity showed that compatibilizer affects the co‐continuity composition range through its effect on the dispersion level of nanoclays. At high EPDM concentration, the continuity of the thermoplastic phase for semi‐exfoliated TPE nanocomposites was higher than in the corresponding TPEs. Considering that TPE formation is the first step for thermoplastic vulcanizate production, where the thermoplastic phase should have a certain level of continuity, these results suggest that higher levels of EPDM could be incorporated into the semi‐exfoliated system before losing matrix continuity. It was also observed that there is a direct relation between the magnitude of the normalized stress growth viscosity overshoot and the continuity of TPE nanocomposites. POLYM. ENG. SCI., 2010. © 2010 Society of Plastics Engineers

The effects of nanoclay dispersion levels and processing parameters on the dynamic vulcanization of TPV nanocomposites based on PP/EPDM prepared by reactive extrusion

“…The materials selected for the present study are described below. They were chosen based on our previous work [18]. General purpose PP homopolymer resin, “Profax” 6523 (Basell Polyolefins), with melt flow index of 4 (g/10 min), was used as the thermoplastic phase.…”

“…Two grades of maleic anhydride‐grafted‐PP (PP‐ g ‐MA), Orevac CA 100 and Orevac 18750 (Arkema), were chosen, in view of our previous study [18], as compatibilizers to prepare PP nanocomposites with different clay dispersion levels. Irganox B 225 (Ciba) primary phenolic type antioxidant was used in order to prevent oxidative degradation of thermoplastic phase.…”

“…This setup is a simplified model of the system used by Dell'Anno [22] to reduce the X‐ray beam intensity in the range of 0.5–4°. More detail could be found in our previous publication [18].…”

“…In a previous publication, we evaluated the effects of different PP‐ g ‐MA compatibilizers on the degree of exfoliation and co‐continuity of TPE nanocomposites based on PP/EPDM [18]. It was shown that the incorporation of clay resulted in a reduction of the continuity index of the EPDM phase.…”

Polyblend Nanocomposites

“…The obtained data showed that the nanocomposites ranged from intercalated tactoids and exfoliated layers. Other investigations suggest that higher levels of EPDM could be incorporated into the semi-exfoliated system before losing matrix continuity (87).…”