The measurements of thermal conductivity of a cement-based composite material are performed in dependence on moisture content from dry state to fully water saturated state using an impulse technique. Then, the obtained data are analyzed using Brugemann and Wiener homogenization formulas. The validity of applied homogenization techniques is assessed comparing the measured and calculated results. On the basis of the experimental data and the homogenization analyses, the effects of total pore volume, pore distribution and moisture content on the thermal conductivity are discussed.
Key words:Thermal conductivity, moisture content, cementitious composites, homogenization
IntroductionCementitious composites contain a significant amount of pores of different size. As the thermal conductivity of the air is 0.026 W/mK [1] and the thermal conductivity of cement stone is (depending on the amount and the type of aggregates) in the range of 1-3 W/mK [2], both the total pore volume and the distribution of pores can affect the thermal conductivity of a cementitious material in a very significant way. In usual service conditions, cementitious composites always contain certain amount of water. The thermal conductivity of water is 0.60 W/mK [1], which is more than 20 times higher than of the air. Therefore, if water is present in the pore space, its effect competes with the effect of air, and the thermal conductivity of a composite material can be considered as a result of this competition together with the effect of the cement matrix.