The Effect of Different AR Nanostructures on the Optical Performance of Organic–Inorganic Halide Perovskite Semiconductor Solar Cell

Abstract

Nanostructures exhibit excellent antireflection (AR) properties allowing for broadband antireflection and increasing the light incoupling in solar cells. In this paper, the optical effect of different nanostructures on the front side of an organic-inorganic halide perovskite semiconductor solar cell is studied. The transfer matrix optical simulation method (TMM) will be used to model and simulate the solar cell while using the effective medium theory (EMT) to model the effective refractive indices of the nanostructures. By optimizing the height of each nanostructure, it was found that the moth-eye nanostructure had the best performance, reducing the reflection by ~ 7.8%, thus enhancing the optical current density by ~ 13.5% and increasing the overall efficiency by 2.22%. Additional optical analysis methods were used to analyze and characterize the effect of the added AR nanostructures such as the solar-weighted reflectance (SWE), the solar absorptance enhancement (SWR), current density loss analysis ( J loss ), and finally, the spectral photovoltaic output (SPV).

Optical loss analysis of Sb2S3 and Sb2Se3 thin film solar cells: A Quantitative Assessment

“…Adding to that is their non-toxic nature, abundant availability, cost-effectiveness, and easy accessibility [3]. Even though both perovskite [4] and antimony chalcogenides have emerged as captivating materials for photovoltaic applications in the last 5 years [5], however, perovskite solar cells suffer from moisture instability which is hindering their upscaling and commercialization [6,7]. The V-VI semiconductor compounds, namely Sb 2 S 3 and Sb 2 Se 3 exhibit remarkable optical and electrical characteristics such as high absorption coefficient (>10 5 cm −1 ), the ability to tune their bandgap within the range of 1.04-1.67 eV, intrinsic p-type conductivity, attired carrier mobility (9-15 cm 2 /V.s), and desirable attributes such as moisture stability [8,9].…”