Aluminates are chemicals made up of ceramic materials based on aluminum oxide as the main constituent. Aluminate materials are widely used in high-technology applications due to their unique properties, for instance, in magnetic materials, ceramic catalysis, absorbent materials, and so forth. 1-4 Spinel is a ceramic oxide with three elements which its general chemical formula is AB 2 O 4 where, in normal spinels, A stands for a bivalent metal cation (A 2+) which occupies a tetrahedral site and B represents a trivalent (B 3+) metal cation which occupies an octahedral site of a cubic lattice. In the same time, in inverse spinels, bivalent cation (A 2+) occupies an octahedral site and a trivalent (B 3+) cation occupies both octahedral and tetrahedral site. 4-6 Nowadays, cobalt aluminate (CoAl 2 O 4) are used as a color pigment in digital ceramic printing, cobalt and gibbsite precursor, catalyst, and color filter. 1-6 Moreover, this kind of spinel is one of the great interests among spinels due to its significant properties such as thermal and chemical stability, 6 optical host matrix, 4 high ability of cation diffusion, 4-7 catalytic application, to name but four. 8-10 Cobalt aluminate conventionally was synthesized by mixing alumina and cobalt oxide, and calcination of the mixture at ~1200°C for an extended period. This type of synthesis requires a long distance diffusion of metal ion that could lead to inhomogeneous and nonstoichiometry spinel. 3 Many novel synthesis methods, like combustion synthesis, 2,11-13 sol-gel, 14,15 low-temperature combustion synthesis (LCS), 3,16 reverse micelle processing, 5 polymeric precursors method, 4 etc. are used to solve these drawbacks. Combustion synthesis (CS) or Self-propagating high-temperature synthesis (SHS) is a potent, and low-cost technique for the synthesis of numerous industrially valuable materials and is used in the fabrication of several ceramic powders for