The study on the implications of digital divide on Students of Ebonyi State University, Abakaliki, was carried out to determine the level of Information and Communication Technology (ICT) knowledge and access among the students in the system. Previous studies carried out in the developed nations such as United States of American, United Kingdom, and Canada and alike had shown that innovative use of ICT facilities has the potentials to effect students teaching/learning. However, literature search of similar studies in the developing nations of the world seems scanty. In order to have a good foundation upon which the study rests, technological determinism theory as propounded by Lievrouw and Livingstone (2006) was adopted. The major interest of the theory is to elucidate the irresistible power of ICT to propel human actions socially and economically for development. Flowing from the assumption of the theory and its focus, the implication of digital divide on students in Nigerian University emerged. The study adopted content analysis approach and reviewing of extent literature. Consequently, the study recommended repositioning the online teaching/learning among students of Ebonyi State University should be made a priority to increase ICT knowledge and access