“…The counter-ion of solution is present in the membrane at a higher concentration than that of the co-ion because of electrostatic interaction. This creates a Donnan potential which could inhibit the permeation of co-ion from solution through RO membrane due to the electrostatic repulsion, resulting in the counter-ion is also rejected in order to maintain electroneutrality [18,33]. In addition, the Donnan's effect governs the permeability which closely relates to the hydrated ionic radius of solutes [23], and the lower permeability counter-ion has higher rejection in balancing the Donnan potential.…”
Section: Effect Of Co-existing Ions On Cs and Sr Rejectionmentioning
“…The counter-ion of solution is present in the membrane at a higher concentration than that of the co-ion because of electrostatic interaction. This creates a Donnan potential which could inhibit the permeation of co-ion from solution through RO membrane due to the electrostatic repulsion, resulting in the counter-ion is also rejected in order to maintain electroneutrality [18,33]. In addition, the Donnan's effect governs the permeability which closely relates to the hydrated ionic radius of solutes [23], and the lower permeability counter-ion has higher rejection in balancing the Donnan potential.…”
Section: Effect Of Co-existing Ions On Cs and Sr Rejectionmentioning
“…Also, brackish water membranes have higher salt passage rates than seawater membranes. Moreover, monovalent ions pass more readily than divalent ions (Bartels et al, 2005).…”
“…R s is a characteristic often used by RO membrane manufactures to describe membrane rejection properties. Typically, RO membranes achieve NaCl rejections of 98e99.8% [40].…”
Section: Dynamic Modeling Of a Spiral-wound Modulementioning
a b s t r a c tAn RO (reverse osmosis) desalination plant is proposed as an effective, FLR (flexible load resource) to be integrated into HES (hybrid energy systems) to support various types of ancillary services to the electric grid, under variable operating conditions. To study the dynamic analysis of such system, special attention is given here to the detailed dynamic modeling and control design of RO desalination process that employs a spiral-wound membrane module. In particular, the solution-diffusion model modified with the concentration polarization theory is applied to predict RO performance over a large range of operating conditions. Simulation results involving several case studies suggest that an RO desalination plant can provide operational flexibility to participate in energy management at the utility scale by dynamically optimizing the use of excess electrical energy. The incorporation of additional commodity (fresh water) produced from a FLR allows a broader range of HES operations for maximizing overall system performance and profitability.Published by Elsevier Ltd.
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