The effect of high rotational quantum numbers on Franck-Condon factors

Reddy, R.R.; Rao, P. Sambasiva; Rao, T. S. S. R. K.

doi:10.1016/0022-4073(82)90046-2

Journal of Quantitative Spectroscopy and Radiative Transfer

1982

DOI: 10.1016/0022-4073(82)90046-2

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The effect of high rotational quantum numbers on Franck-Condon factors

R.R. Reddy¹,

P. Sambasiva Rao²,

T. S. S. R. K. Rao³

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1983

1991

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Cited by 2 publications

References 11 publications

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Problems in the description of the intensities of electronic spectra of diatomic molecules in the adiabatic approximation

Кузьменко¹,

Kuznetsova²,

Kuzyakov³

1983

Sov. Phys. Usp.

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The local single-particle correlation function for the symmetric Wolff model is evaluated at zero temperature in the weak-coupling-longtime limit by a stationary-phase argument. The leading behaviour is given by an asymptotic expansion in the coupling strength. The correlation function furthermore has a weak essential singularity at vanishing coupling strength, corresponding to the exponential decay of transient Fermi surface effects, and is scale invariant under a simultaneous change of time scale and coupling-strength scale. In the intermediate and strong coupling regime the calculation breaks down due to manybody effects. Comments are made on some frequently used operator representations and some recent work by Mattis.

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Problems in the description of the intensities of electronic spectra of diatomic molecules in the adiabatic approximation

Кузьменко¹,

Kuznetsova²,

Kuzyakov³

1983

Sov. Phys. Usp.

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Rapid tuning cw laser technique for measurements of gas velocity, temperature, pressure, density, and mass flux using NO

et al. 1991

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An intracavity-doubled rapid-tuning cw ring dye laser was used to acquire fully resolved absorption profiles of NO line pairs in the A ? X band at 225 nm at a rate of 4 kHz. These profiles were utilized for simultaneous measurements of flow parameters in the high speed 1-D flows generated in a shock tube. Velocity was determined from the Doppler shift measured using a pair of profiles simultaneously acquired at different angles with respect to the flow direction. Temperature was determined from the intensity ratio of the adjacent lines. Pressure and density were found both from the collisional broadening and the fractional absorption. From this information the mass flux was determined. The results compare well to 1-D shock calculations.

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The effect of high rotational quantum numbers on Franck-Condon factors

Cited by 2 publications

References 11 publications

Problems in the description of the intensities of electronic spectra of diatomic molecules in the adiabatic approximation

Problems in the description of the intensities of electronic spectra of diatomic molecules in the adiabatic approximation

Rapid tuning cw laser technique for measurements of gas velocity, temperature, pressure, density, and mass flux using NO

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