Paper is a flexible material, commonly used for information storage, writing, packaging or specialized purposes. It also has strong appeal as a substrate in the field of flexible printed electronics. Many applications, including safety, merchandising, smart labels/packing, chemical/biomedical sensors, require an energy source to power operation. Here we review progress regarding development of photovoltaic and energy storage devices on cellulosic substrates where one or more of the main material layers are deposited via solution processing or printing. Paper can be used simply as the flexible substrate or, exploiting its porous fibrelike nature, as an active film by infiltration or co-preparation with electronic materials. Solar cells with efficiencies of up to 4% on opaque and 9% on transparent substrates have been demonstrated. Recent developments in paper-based supercapacitors and batteries are also reviewed with maximum achieved capacity of 1350 mF cm -2 and 2000 mAh g -1 respectively.Analysing the literature, it becomes apparent that more work needs to be carried out in continuing to improve peak performance, but especially stability and the application of printing techniques, even roll-to-roll, over large areas. Paper is not only environmentally friendly and recyclable, it is thin, flexible, low-weight, biocompatible, and low-cost.