The effect of Li2CO3 substitution on synthesis of LiBOB compounds as salt of electrolyte battery lithium ion

Lestariningsih, Titik; Wigayati, Etty Marty; Sabrina, Qolby; Prihandoko, Bambang; Priyono, Slamet

doi:10.1063/1.5030250

Cited by 3 publications

(5 citation statements)

References 10 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…It was then compared with LiBOB salt synthesized without vacuum condition at temperature of 240 o C, referring to experiments by Bi Tao Yu et al [4] and Lestariningsih T et al [5]. Synthesis process without vacuum was performed in Thermoline muffle furnace while synthesis process in vacuum condition was done using oven Songling Chinese type SBVO-03.…”

Section: Experimental Methodsmentioning

confidence: 99%

“…Many researches have been conducted about synthesis LiBOB such as ones that have been done by Bi-Tao Yu et al [4] and Lestariningsih T et al [5] synthesized LiBOB from the analytical grade material by the method of solid state reaction (powder metallurgy).…”

Section: Introductionmentioning

confidence: 99%

“…In this research, synthesis and characterization of LiBOB compound was performed by heat treatment under vacuum condition with reference to the research that has been done by Zhang Juan Li et al [6]. As additional reference, heat treatment without employing vacuum condition refers to experiments conducted by Bi-Tao Yu [4] and Lestariningsih T. [5]. One of the important processes in the synthesis of LiBOB compound is the heat treatment.…”

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Study of LiBOB compound synthesis by vacuum process as lithium ion battery electrolytes

Lestariningsih

Wigayati

Ratri

et al. 2017

J. Phys.: Conf. Ser.

View full text Add to dashboard Cite

Abstract. Lithium bis (oxalato) borate or LiBOB is potential candidate to substitute LiPF 6 which has many problems in lithium ion batteries. Many studies have been synthesized of electrolyte salt LiBOB to improve performance as electrolyte lithium ion batteries. In this paper we have studied the synthesis of compounds LiBOB undergoing pre-heat treatment in a vacuum. LiBOB was synthesized by mixing technical grade raw materials H2C2O4.2H2O, LiOH and H3BO3. The mixture H2C2O4.2H2O and LiOH was preheated at 60 °C for 2 h before adding H3BO3 in several time to be mortared in vacuum dryer, the mixture of the three starting materials was preheated in two steps at 70 °C for 6 h and the third step of preheating at a temperature of 100 °C. This powder was then characterized using XRD, FTIR and BET. The characterization results of LiBOB compared to commercial LiBOB powder. The XRD analysis results showed that the sample have formed LiBOB and LiBOB hydrate phase, while FTIR analysis results show the formation of functional groups of LiBOB. In addition, the BET results shows the surface area of synthesized LiBOB is 75.994 m 2 /g, close the surface area of commercial LiBOB, i.e 108.776 m 2 /g.

show abstract

Section: Experimental Methodsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Study of LiBOB compound synthesis by vacuum process as lithium ion battery electrolytes

Lestariningsih

Wigayati

Ratri

et al. 2017

J. Phys.: Conf. Ser.

View full text Add to dashboard Cite

show abstract

“…However, they improved the purity of anhydrous LiBOB only up to 59.1% using Li 2 CO 3 instead of LiOH which yielded only 17.2% pure anhydrous product. 34,36 Lian and his group performed a rheological phase reaction using oxalic acid dihydrate, lithium hydroxide monohydrate, and boric acid. They reported that LiBOB synthesized from a solid-state reaction may suffer from impurities requiring additionally recrystallization steps.…”

Section: ■ Introductionmentioning

confidence: 99%

“…Yu et al employed a solid-state reaction for the first time using oxalic acid, lithium hydroxide, and boric acid as starting materials followed by a thermal treatment in air and a recrystallization process to obtain LiBOB; in addition, they also reported that LiBOB decomposes into Li 2 C 2 O 3 , B 2 O 3 , CO 2 , and CO at temperatures higher than 300 °C. , In another study, Lestariningsih and co-workers utilized lithium carbonate instead of lithium hydroxide to eliminate the LiBOB·H 2 O phase. However, they improved the purity of anhydrous LiBOB only up to 59.1% using Li 2 CO 3 instead of LiOH which yielded only 17.2% pure anhydrous product. , Lian and his group performed a rheological phase reaction using oxalic acid dihydrate, lithium hydroxide monohydrate, and boric acid. They reported that LiBOB synthesized from a solid-state reaction may suffer from impurities requiring additionally recrystallization steps .…”

Section: Introductionmentioning

confidence: 99%

Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB)

et al. 2021

View full text Add to dashboard Cite

Lithium bis(oxalate)borate, LiB(C 2 O 4 ) 2 (LiBOB), is one of the most important electrolyte additives for Li-ion batteries (LIBs) due to its numerous advantages such as thermal stability, good solubility in organic solvents, high conductivity, and low cost as well as providing safer operations with superior electrochemical performance compared to conventional electrolyte combinations. However, the use of LiBOB is limited due to slight instability issues under ambient conditions that might require extra purification steps and might result in poorer performances in real systems. Here, we address some of these issues and report the high purity water free LiBOB synthesized with fewer processing steps employing lithium carbonate, oxalic acid, and boric acid as lowcost starting materials, and via ceramic processing methods under protective atmosphere. The physical and chemical characterizations of both anhydrous and monohydrate phases are performed with X-ray powder diffraction (XRPD), Fourier-transform infra-red spectroscopy (FTIR), Raman spectroscopy and scanning electron microscopy (SEM) analyses to determine the degree of the purity and the formation of impurities like LiBOB.H 2 O, HBO 2 and Li 2 C 2 O 4 as a result of the aging investigations performed. Differential thermal analysis (DTA) is applied to determine the optimum synthesis conditions for anhydrous LiBOB and to analyze the water loss and the decomposition of LiBOB.H 2 O. Aging experiments with the water free LiBOB are carried out to evaluate the effect of humidity in the phase changes and resulting impurities under various conditions. The detrimental effect of even slightest humidity conditions is shown, and protective measures during and after the synthesis of LiBOB are discussed. Anhydrous LiBOB could be widely used as an electrolyte additive to improve the overall electrochemical performances for LIBs through development of a protective solid electrolyte interphase (SEI) on the surface of high voltage cathodes and bringing about superior electrochemical properties with increased cycling stability, rate capability and coulombic efficiency, if synthesized, purified, and handled properly before use in real electrochemical systems.

show abstract

The effect of LiBOB additives produced from brine water as a lithium source on the electrochemical performance of NCM cathodes for lithium-ion batteries

Lestariningsih,

Subhan,

Sabrina

et al. 2024

5TH INTERNATIONAL SEMINAR ON METALLURGY AND MATERIALS (ISMM2022): Strengthening Research and Innovation in Metallurgy and Mater

View full text Add to dashboard Cite

The effect of Li2CO3 substitution on synthesis of LiBOB compounds as salt of electrolyte battery lithium ion

Cited by 3 publications

References 10 publications

Study of LiBOB compound synthesis by vacuum process as lithium ion battery electrolytes

Study of LiBOB compound synthesis by vacuum process as lithium ion battery electrolytes

Guide to Water Free Lithium Bis(oxalate) Borate (LiBOB)

The effect of LiBOB additives produced from brine water as a lithium source on the electrochemical performance of NCM cathodes for lithium-ion batteries

Contact Info

Product

Resources

About