“…Sensitisation of Al-Mg alloys in naval service has proved difficult to avoid, and IG-SCC of marine structures, where residual stress levels can be high, is increasingly common [3,23]. Numerous research efforts have confirmed that a coupled anodic dissolution (of the β/α-Al matrix) and hydrogen embrittlement mechanism drives IG-SCC [5,13,14,16,17,[24][25][26][27][28]. Specifically, localised anodic β phase dissolution at the crack-tip provides Al 3+ and Mg 2+ cations in the local crack-tip chemistry that (1) promote metal cation hydrolysis reactions to form hydrogen, (2) drive Cl − ingress for charge neutralisation, which in turn (3) affects the complex oxide at the crack tip to enable further α-Al matrix dissolution [24,[29][30][31].…”