Metallized textiles have shown promising applications in the elds of electrical conductivity, Joule heating and electromagnetic shielding. Poor durabilities, especially washability, which caused by the signi cant mechanical mismatch between rigid metal parts and textiles have hindered commercialization process of these functional textiles. This work constructed ultra-durable conductive cotton fabrics by growing copper nanoparticles with amorphous region-controlled swelling and multivalent bonding forces to complex the metal particles. The enlarged ber amorphous zone and phen-amine molecules are used as templates to provide further possibilities for the internal and external enrichment growth of copper nanoparticles, providing good conductivity and high durability of the processed cotton fabric. The constructed fabric exhibits excellent electrical conductivity (6.09±0.36×10 -3 Ω/sq), electrothermal conversion (60 s, 1 V, ~140 °C) and electromagnetic shielding e ciency (65.32 dB). Notably, the electrical conductivity of the fabric remains essentially unchanged (Rs/R 0 =1.106) after 100 standard washing tests. This is attributed to the increase in metal particle loading and the enhancement of metal-ber bonding fastness. Therefore, this work might provide a novel insight for constructing ultra-washable conductive clothing textiles with heating and EMI shielding performance.