The effect of salt concentration on the PEO–LiClO4–lithium electrode interfacial resistivity

Bac, A.; Ciosek, Marcin; Bukat, M.; Siekierski, Maciej; Wieczorek, W.

doi:10.1016/j.jpowsour.2006.02.039

Cited by 18 publications

(19 citation statements)

References 16 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…4(b)] corresponding to the CH 2 wagging mode. 30,38 The bands observed in Fig. 4(c) at 964 and 949 cm −1 are primarily due to the C-O stretching modes with a slight contribution arising from CH 2 rocking motion.…”

Section: Resultsmentioning

confidence: 96%

“…4(a) triplet peaks, observed with maxima at 1144, 1107 and 1062 cm −1 corresponding to C-O-C stretching vibrations, are the evidence for the presence of crystalline PEO phase. 30,38 The crystallinity of PEO can also be confirmed by the presence of doublet peaks at 1360 and 1343 cm −1 [ Fig. 4(b)] corresponding to the CH 2 wagging mode.…”

Section: Resultsmentioning

confidence: 97%

“…All these experimental results suggest that the addition of EMITf changes the local chain organization considerably. 30 To study the ion-ion interaction in these electrolytes the symmetric deformation mode of CF 3 [denoted as δ s (CF 3 )] in the spectral region 770-745 cm −1 has been investigated and is shown in Fig. 5(a).…”

Section: Resultsmentioning

confidence: 99%

“…Thus, the ionic conductivity is greatly affected by the nature of the ionic species present in a polymer electrolyte. [28][29][30] Neutral ion pairs or neutral multiplets (as they carry no charge) do not contribute to the conductivity and thus the number of carriers available for conduction is reduced.…”

Section: Introductionmentioning

confidence: 99%

See 3 more Smart Citations

Structure and ionic conductivity of ionic liquid embedded PEO- LiCF3SO3 polymer electrolyte

Karmakar

Ghosh

2014

AIP Advances

View full text Add to dashboard Cite

In this paper we have reported electrical and other physical properties of polyethylene oxide (PEO) - LiCF3SO3 polymer electrolytes embedded with 1-ethyl-3-methylimidazolium trifluoromethanesulfonate ionic liquid. The addition of the ionic liquid to PEO- LiCF3SO3 electrolyte increases the amorphous phase content considerably and decreases the glass transition temperature. The relative amounts of different ionic species present in these electrolytes have been determined. It is observed that the fraction of free anions increase with the increase of ionic liquid concentration, whereas the fraction for ion pairs and aggregates show a decreasing trend under the same condition. The ionic conductivity of the PEO- LiCF3SO3 polymer electrolyte embedded with ionic liquid is higher than that of the PEO- LiCF3SO3 electrolyte. The ionic conductivity shows a transition around 323 K. The ionic conductivity above 323 K exhibits Arrhenius behavior with an activation energy, which decreases with the increase of ionic liquid concentration. However, below 323 K the conductivity shows Vogel–Tamman–Fulcher (VTF) type behavior.

show abstract

Section: Resultsmentioning

confidence: 96%

Section: Resultsmentioning

confidence: 97%

Section: Resultsmentioning

confidence: 99%

Section: Introductionmentioning

confidence: 99%

See 2 more Smart Citations

Structure and ionic conductivity of ionic liquid embedded PEO- LiCF3SO3 polymer electrolyte

Karmakar

Ghosh

2014

AIP Advances

View full text Add to dashboard Cite

show abstract

“…The reason of the two component separation is not clear. According to the previous paper, two kinds of interfaces, stable SEI and unstable SEI, formed at the electrode|electrolyte interface [17]. Along with this concept, the semicircle A and B would be ascribed to the stable and unstable SEI.…”

Section: Resultsmentioning

confidence: 88%

Fabrication of all solid-state lithium polymer secondary batteries using PEG-borate/aluminate ester as plasticizer for polymer electrolyte

2007

View full text Add to dashboard Cite

A Polymer‐Electrolyte‐Based Atomic Switch

Tsuruoka

Terabe

et al. 2010

Adv Funct Materials

134

121

View full text Add to dashboard Cite

Studies on a resistive switching memory based on a silver‐ion‐conductive solid polymer electrolyte (SPE) are reported. Simple Ag/SPE/Pt structures containing polyethylene oxide–silver perchlorate complexes exhibit bipolar resistive switching under bias voltage sweeping. The switching behavior depends strongly on the silver perchlorate concentration. From the results of thermal, transport, and electrochemical measurements, it is concluded that the observed switching originates from formation and dissolution of a silver metal filament inside the SPE film caused by electrochemical reactions. This is the first report of an electrochemical “atomic switch” realized using an organic material. The devices also show ON/OFF resistance ratios greater than 105, programming speeds higher than 1 μs, and retention times longer than 1 week. These results suggest that SPE‐based electrochemical devices might be suitable for flexible switch and memory applications.

show abstract

The effect of salt concentration on the PEO–LiClO4–lithium electrode interfacial resistivity

Cited by 18 publications

References 16 publications

Structure and ionic conductivity of ionic liquid embedded PEO- LiCF3SO3 polymer electrolyte

Structure and ionic conductivity of ionic liquid embedded PEO- LiCF3SO3 polymer electrolyte

Fabrication of all solid-state lithium polymer secondary batteries using PEG-borate/aluminate ester as plasticizer for polymer electrolyte

A Polymer‐Electrolyte‐Based Atomic Switch

Contact Info

Product

Resources

About