There are thousands of adjuvants on the market, yet little is known about their effects on the activity of insecticides on plant surfaces. The effects of 11 selected adjuvants on the rainfastness and retention of bifenthrin -(i-)-(2 methyl[l,l'-biphenyl]-3-yl) methyl 3-(2-chloro-3J,3-trifluoro-l-propenyl)-2~-dimethylcyclopropanearhoxylate) on cotton (Gossypium hirsutum L.) leaves were investigated. In addition, the effect of the adjuvant Bond on the efficacy of bifenthrin and a Bacillus thuringiensis (Berliner) formulation wa9 determined. Bifenthrin mixed with each adjuvant was applied to greenhouse grown cotton plants using a spray chamber. Simulated rainfall of 13 mm was then applied to treated cotton plants at 0.25, 1, and 4 h after treatment. Bond and Agimax-3 were the only adjuvant. to significantly increase the rainfastness of hifenthrin on cotton leaves. Agri-Dex, Soy-Dex, and Dyne-Amic significantly decreased the rainfaqtness of bifenthrin. In tests conducted with an immersion cell apparatus, Orchex 7% resulted in twice the retention of Agri-Dex, the nkit highest retained adjuvant. Both petroleum and veget-able oils enhanced retention of bifenthrin on the leaf surface. Bond mixed with bifenthrin m d a B. thuringiensis formulation did not reduce the activity of these insecticides against tobacco hudworm (Heliothis virescens) and soybean looper (Pseudoplusia includens) larvae. Retention on the leaf may he related to spread and to the degree of binding of the insecticide to the surface by properties of the adjuvant. Yet, the properties of Agri-Dex that enhanced the retention of bifenthrin to the cotton leaf decreased its rainfastness.
SPRAY adjuvants may enhance pesticide activity and minimize the effects of environmental factors on pesticide application and decomposition. Thousands of adjuvants are now on the market. Foy (1993), in a survey of product labels from 485 formulations of crop protection chemicals for use in 1992, found that 49% of the formulations recommended adjuvant use, 5% recommended no adjuvant, and the remaining 46% did not mention adjuvant use. Adjuvants were recommended with 71% of the herbicide formulations and with 30% of the other classes of crop protection chemicals, while 14% of the other classes of crop protection chemicals did not recommend an adjuvant.The greatest reduction of pesticide efficacy results from environmental factors. While sunlight gradually decomposes pesticides on the leaf surface, rainfall has an immediate effect on the adherence of pesticide residues to plant surfaces, especially if a storm occurs shortly after application.Studies have shown that rainfall amount more greatly affects the washoff of insecticides from cotton plants than does rainfall intensity. However, the effect of elapsed time between insecticide application and rainfall on insecticide washoff from plants varies with insecticide and/or formulation. For example, methyl parathion that is washed from cotton plants decreases exponentially with time after application and linearly with the co...